跳转至内容
Merck
CN
所有图片(3)

主要文件

查看所有文档

安全信息

918105

Sigma-Aldrich

(MeBPI)2Ni

≥95%

登录查看公司和协议定价
所有图片(3)

About This Item

经验公式（希尔记法）:
C40H32N10Ni
CAS号:
78065-33-5
分子量:
711.44
MDL编号:
MFCD33021718
UNSPSC代码:
12352103
NACRES:
NA.22

质量水平

100

方案

≥95%

表单

crystals

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES字符串

[Ni+2].[N-]5\C(=N\c8nccc(c8)C)\c6c(cccc6)\C\5=N/c7nccc(c7)C.[N-]1\C(=N\c4nccc(c4)C)\c2c(cccc2)\C\1=N/c3nccc(c3)C

InChI key

UEBWUPHCLCWDLU-UHFFFAOYSA-N

相关类别

应用

(MeBPI)2Ni is a redox-active shuttle developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with (MeBPI)Ni-OAc (919365), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

其他说明

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

相关产品

产品编号
说明
价格

919365

(MeBPI)Ni-OAc

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our 文件 section.

如需帮助，请联系 客户支持

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门