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表单
powder
质量水平
反应适用性
reagent type: catalyst
reaction type: Cross Couplings
SMILES字符串
[Pd+]c%10ccc(cc%10)C(F)(F)F.Fc1c(c(c(c(c1CCCC)F)F)c2c(c(c(cc2C(C)C)C(C)C)c3c(c(ccc3)OC)P([C@]87C[C@H]9C[C@@H](C8)C[C@@H](C7)C9)[C@]54C[C@H]6C[C@@H](C5)C[C@@H](C4)C6)C(C)C)F.FC(F)(F)[S](=O)(=O)[O-]
InChI key
QJLVEPMTRMVTFU-HZBKTHAQSA-M
应用
AlPhos Pd G6 OTf is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
Learn more about G6 Buchwald precatalysts
Learn more about G6 Buchwald precatalysts
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts
商品
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
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