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916455

Sigma-Aldrich

AlPhos Pd G6 OTf

别名:

AlPhos OAC precatalyst OTf

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100 MG
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100 MG
CN¥4,971.74

About This Item

经验公式（希尔记法）:
C60H71F10O4PPdS
CAS号:
2097600-18-3
分子量:
1215.65
UNSPSC代码:
12352100
NACRES:
NA.22

CN¥4,971.74

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表单

powder

质量水平

100

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

SMILES字符串

[Pd+]c%10ccc(cc%10)C(F)(F)F.Fc1c(c(c(c(c1CCCC)F)F)c2c(c(c(cc2C(C)C)C(C)C)c3c(c(ccc3)OC)P([C@]87C[C@H]9C[C@@H](C8)C[C@@H](C7)C9)[C@]54C[C@H]6C[C@@H](C5)C[C@@H](C4)C6)C(C)C)F.FC(F)(F)[S](=O)(=O)[O-]

InChI key

QJLVEPMTRMVTFU-HZBKTHAQSA-M

相关类别

应用

AlPhos Pd G6 OTf is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

其他说明

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

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产品编号
说明
价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

  • 技术规格说明书

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    Lot/Batch Number
    MKCM6724
    SHBN8360

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    Bryan T Ingoglia et al.
    Organic letters, 19(11), 2853-2856 (2017-05-13)
    In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

    商品

    Buchwald G6 Precatalysts: Oxidative Addition Complexes

    Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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