推荐产品
检测方案
≥95%
形式
powder or crystals
储存温度
2-8°C
应用
cis-Hexamethylphosphetane oxide is a phosphetane oxide-based organocatalyst used for reductive C-N cross couplings.
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Trevor V Nykaza et al.
Angewandte Chemie (International ed. in English), 59(11), 4505-4510 (2019-12-24)
An organocatalytic method for the modular synthesis of diverse N-aryl and N-alkyl azaheterocycles (indoles, oxindoles, benzimidazoles, and quinoxalinediones) is reported. The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane P-oxide) and a hydrosilane reductant to drive the conversion of ortho-functionalized nitroarenes
Intermolecular Reductive C-N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis.
Trevor V Nykaza et al.
Journal of the American Chemical Society, 140(45), 15200-15205 (2018-10-30)
A main group-catalyzed method for the synthesis of aryl- and heteroarylamines by intermolecular C-N coupling is reported. The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane) and a terminal hydrosilane reductant (phenylsilane) to drive reductive intermolecular coupling of nitro(hetero)arenes with boronic
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