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913219

Sigma-Aldrich

(S,S)-BABIBOP

别名:

(3S,3′S)-3,3′-Di-tert-butyl-2,2′,3,3′-tetrahydro-4,4′-bibenzo[d][1,3]oxaphosphole

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About This Item

经验公式（希尔记法）:
C22H28O2P2
CAS号:
2207601-04-3
分子量:
386.40
UNSPSC代码:
12352200

表单

powder

光学纯度

ee: ≥99% (HPLC)

反应适用性

reagent type: ligand

官能团

phosphine

应用

(S,S)-BABIBOP is a P-chiral biaryl biphosphorus ligand used in Pd, Cu, and Rh-catalyzed asymmetric hydrogenations.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

其他说明

BABIPhos Family of Biaryl Dihydrobenzooxaphosphole Ligands for Asymmetric Hydrogenation

法律信息

Sold in collaboration with Zejun Pharmaceuticals

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价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Olga V Zatolochnaya et al.
Chemical science, 9(19), 4505-4510 (2018-06-14)
A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolution, simultaneously creating two contiguous stereogenic centers with
Guisheng Li et al.
Organic letters, 20(7), 1725-1729 (2018-03-16)
Novel bidentate phosphine ligands BABIPhos featuring a biaryl bis-dihydrobenzooxaphosphole core are presented. Their synthesis was achieved via Pd-catalyzed reductive homocoupling of dihydrobenzooxaphosphole aryl triflates. An efficient route toward various analogues was also established, giving access to phosphines with different electronic

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