913219
(S,S)-BABIBOP
powder
别名:
(3S,3′S)-3,3′-Di-tert-butyl-2,2′,3,3′-tetrahydro-4,4′-bibenzo[d][1,3]oxaphosphole
产品名称
(S,S)-BABIBOP,
form
powder
optical purity
ee: ≥99% (HPLC)
reaction suitability
reagent type: ligand
functional group
phosphine
Application
(S,S)-BABIBOP is a P-chiral biaryl biphosphorus ligand used in Pd, Cu, and Rh-catalyzed asymmetric hydrogenations.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Legal Information
Sold in collaboration with Zejun Pharmaceuticals
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Guisheng Li et al.
Organic letters, 20(7), 1725-1729 (2018-03-16)
Novel bidentate phosphine ligands BABIPhos featuring a biaryl bis-dihydrobenzooxaphosphole core are presented. Their synthesis was achieved via Pd-catalyzed reductive homocoupling of dihydrobenzooxaphosphole aryl triflates. An efficient route toward various analogues was also established, giving access to phosphines with different electronic
Olga V Zatolochnaya et al.
Chemical science, 9(19), 4505-4510 (2018-06-14)
A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolution, simultaneously creating two contiguous stereogenic centers with
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