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Merck
CN
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文件

安全信息

912255

Sigma-Aldrich

sBOX(tBu)

≥95%

别名:

Di-tert-butyl 2,2′-(cyclopropane-1,1-diyl)(4S,4′S)-bis(4,5-dihydrooxazole-4-carboxylate)

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About This Item

经验公式（希尔记法）:
C19H28N2O6
CAS号:
2328084-27-9
分子量:
380.44
UNSPSC代码:
12352005
NACRES:
NA.22

检测方案

≥95%

形式

powder or solid

mp

120.5 °C

储存温度

2-8°C

相关类别

应用

sBOX(tBu) is a serine-derived chiral bisoxazoline ligand. The additional coordinating functionality provided by the esters enables new reactivity compared to traditional BOX ligands. sBOX(iPr) has been shown to be an optimal ligand for the electrocatalytic cyanophosphorylation as well as hydrocyanation of vinylarenes.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

其他说明

New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Niankai Fu et al.
Journal of the American Chemical Society, 141(37), 14480-14485 (2019-09-10)
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new

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