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表单
(Powder or Solid or Chunks)
环保替代产品特性
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
环保替代产品分类
, Aligned
储存温度
−20°C
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此商品 | A1645 | 09709 | 88431 |
|---|---|---|---|
| assay ≥98% | assay ≥98.5% | assay ≥99.5% (T) | assay ≥99.5% (T) |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| grade ACS reagent, anhydrous | grade - | grade - | grade analytical standard |
| anion traces chloride (Cl-): ≤5 ppm, sulfate (SO42-): ≤0.01%, nitrate (NO3-): ≤0.001% | anion traces - | anion traces chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤50 mg/kg | anion traces - |
| pH 3.8-4.4 (25 °C, 5%) | pH 3.8-4.4 (25 °C, 50 g/L) | pH 4.0-5.0 (25 °C, 0.1 M in H2O) | pH 3.8-4.4 (25 °C, 50 mg/mL in H2O) |
一般描述
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase the catalytic efficiency and acts as an environmentally benign and sustainable amphiphile. Find details here.
应用
PS-750-M is a custom surfactant developed in the Handa lab. PS-750-M allows for a variety of reactions, including challenging cross-couplings and monofluorination of indoles, to be conducted in water.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions
Brals J, et al.
ACS Catalysis, 10, 7245-7250 (2017)
Lucie Finck et al.
The Journal of organic chemistry, 83(14), 7366-7372 (2018-02-10)
Using micelles of FI-750-M, visible light, photocatalysts, and inexpensive halogenating reagents, such as N-bromosuccinimide and N-chlorosuccinimde, selective oxyhalogenations of alkynes were achieved in water under very mild conditions. No halogenation at the aromatic rings was detected, and control experiments revealed
Shielding Effect of Micelle for Highly Effective and Selective Monofluorination of Indoles in Water.
Pranjal P Bora et al.
ChemSusChem, 12(13), 3037-3042 (2019-03-06)
Highly selective direct monofluorination of indoles and arenes was developed through an approach that allows site-specific solubility of substrate and fluorine source in the micelle. This approach was highly selective for a broad range of substrates with excellent functional group
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