90660
三苄胺
≥99.0% (NT)
别名:
TBA
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关于此项目
线性分子式:
(C6H5CH2)3N
化学文摘社编号:
分子量:
287.40
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-638-3
Beilstein/REAXYS Number:
2214682
MDL number:
Assay:
≥99.0% (NT)
Form:
powder
InChI key
MXHTZQSKTCCMFG-UHFFFAOYSA-N
InChI
1S/C21H21N/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2
SMILES string
C(N(Cc1ccccc1)Cc2ccccc2)c3ccccc3
assay
≥99.0% (NT)
form
powder
mp
91-94 °C (lit.)
functional group
amine, phenyl
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Application
三苄胺（TBA）是一种叔胺，可以用作：
TBA 还可以在硝酸铈铵（CAN）存在下进行脱苄基反应以形成二苄胺。
- 涉及 C−N 键形成反应的氮基源；
- 用于通过有氧氧化缩合反应合成亚胺，即 N−亚苄基苄胺。
- 作为萃取剂，用于分离和测定废水中的 Cr（VI）和Cr（III）。
TBA 还可以在硝酸铈铵（CAN）存在下进行脱苄基反应以形成二苄胺。
signalword
Warning
hcodes
Hazard Classifications
Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
399.2 °F - closed cup
flash_point_c
204 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Copper-Catalyzed Oxidative Amination of Benzoxazoles via C- H and C- N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources.
Guo S, et al.
Organic Letters, 13(3), 522-525 (2010)
Céline Burnier et al.
Talanta, 192, 135-141 (2018-10-24)
Nowadays, Gas Chromatography Mass Spectrometry (GC-MS) is mainly used in forensic sciences but suffers from limitations when the analysed compounds are thermally instable as it is the case for THC-A (Tetrahydrocannabinolic Acid) which is converted into Δ9-THC (Δ9-Tetrahydrocannabinol) that subsequently
Highly active and selective gold catalysts for the aerobic oxidative condensation of benzylamines to imines and one-pot, two-step synthesis of secondary benzylamines.
Grirrane A, et al.
J. Catal., 264(2), 138-144 (2009)
Chemoselective oxidative debenzylation of tertiary N-benzyl amines.
Bull SD, et al.
Chemical Communications (Cambridge, England), 165(5), 337-338 (2000)
Yan Qu et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 58(9-10), 640-642 (2003-10-28)
Two compounds, (p-methoxyphenyl) diphenylmethanol (1) and tribenzylamine (2), were isolated from Humulus lupulus. Their structures were established on the basis of spectral evidence (MS, IR, NMR, HMBC, HMQC, 1H-1H COSY experiments). Compounds 1 and 2 were found as natural products
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