描述
Band gap: 1.95 eV
Solubility:Soluble in 1,2-Dichlorobenzene
形式
particles
分子量
50,000-100,000 g/mol by GPC
颜色
Fine
溶解性
chlorobenzene: soluble
chloroform: soluble
轨道能量
HOMO -5.52 eV
LUMO -3.57 eV
PDI
2‑4
相关类别
应用
High-Efficiency Organic Solar Cells (OPVs)
Polymeric donor material
LUMO=−3.57 eV
HOMO=−5.32 eV
OPV Device Performance :
PBDB-T-2Cl:IT-4F
Voc= 0.86V
Jsc= 21.46 mA/cm2
FF= 0.75
PCE=13.9%
PBDB-T-2Cl (or PM7) is a wide bandgap polymer donor (n-type semiconductor) containing chlorinated thienyl benzodithiophene (BDT-2Cl) used in high performance polymer solar cells (PSCs). PBDB-T-2Cl-based devices exhibit higher open circuit voltage (Voc) than the PBDB-T-2F-based devices, due to lower molecular energy levels of PBDB-T-2Cl, and leading to an outstanding power conversion efficiency of over 14%.
In general, chlorination is more effective than fluorination in downshifting the molecular energy levels and broadening the absorption spectra.
Polymeric donor material
LUMO=−3.57 eV
HOMO=−5.32 eV
OPV Device Performance :
PBDB-T-2Cl:IT-4F
Voc= 0.86V
Jsc= 21.46 mA/cm2
FF= 0.75
PCE=13.9%
PBDB-T-2Cl (or PM7) is a wide bandgap polymer donor (n-type semiconductor) containing chlorinated thienyl benzodithiophene (BDT-2Cl) used in high performance polymer solar cells (PSCs). PBDB-T-2Cl-based devices exhibit higher open circuit voltage (Voc) than the PBDB-T-2F-based devices, due to lower molecular energy levels of PBDB-T-2Cl, and leading to an outstanding power conversion efficiency of over 14%.
In general, chlorination is more effective than fluorination in downshifting the molecular energy levels and broadening the absorption spectra.
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Fluorination vs. chlorination: a case study on high performance organic photovoltaic materials.
Science China: Chemistry, 61(10), 1328-1337 (2018)
Over 14% Efficiency in Polymer Solar Cells Enabled by a Chlorinated Polymer Donor.
Advanced Mat., 30(20) (2018)
商品
Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.
我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门