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Merck
CN

903698

Sigma-Aldrich

1-Isopropyl-4-methyl-5-norbornene

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别名:
1-Isopropyl-4-methylbicyclo[2.2.1]hept-2-en
经验公式(希尔记法):
C11H18
分子量:
150.26
UNSPSC代码:
12352200

形式

liquid

反应适用性

reaction type: C-H Activation
reagent type: catalyst

储存温度

2-8°C

应用

1-Isopropyl-4-methyl-5-norbornene is a norbornene ligand developed in the lab of Guanbing Dong for us in norbornene/palladium catalysis. The catalytic system of 1-Isopropyl-4-methyl-5-norbornene, [PdCl(allyl)]2 (683396), and RuPhos (663131) can be used for the site-selective ortho functionalization of aryl iodides.1

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Jianchun Wang et al.
Nature chemistry, 10(8), 866-872 (2018-06-27)
Achieving site-selectivity in arene functionalization that is complementary to the site-selectivity from electrophilic aromatic substitution reactions has been a long-standing quest in organic synthesis. Palladium/norbornene cooperative catalysis potentially offers a unique approach to this problem, but its use has been

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