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Merck
CN
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安全信息

903647

Sigma-Aldrich

1-Heptyl-2-norbornene

≥95%

别名:

1-Heptylbicyclo[2.2.1]hept-2-ene

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About This Item

经验公式（希尔记法）:
C14H24
CAS号:
2237928-10-6
分子量:
192.34
UNSPSC代码:
12352200

方案

≥95%

表单

liquid

反应适用性

reaction type: C-H Activation
reagent type: catalyst

应用

1-Heptyl-2-norbornene is a norbornene ligand developed in the lab of Guanbing Dong for us in norbornene/palladium catalysis. The catalytic system of 1-Heptyl-2-norbornene, [PdCl(allyl)]2 (683396), and RuPhos (663131) can be used for the site-selective ortho functionalization of aryl iodides.1

其他说明

Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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历史批次信息供参考:

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Jianchun Wang et al.
Nature chemistry, 10(8), 866-872 (2018-06-27)
Achieving site-selectivity in arene functionalization that is complementary to the site-selectivity from electrophilic aromatic substitution reactions has been a long-standing quest in organic synthesis. Palladium/norbornene cooperative catalysis potentially offers a unique approach to this problem, but its use has been

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