检测方案
≥95%
形式
powder
反应适用性
reagent type: catalyst
reaction type: Photocatalysis
mp
94 °C
光触媒活化
365 nm
SMILES字符串
C12=CC=CC=C1SC3=C(C=CC=C3)N2C4=CC=CC=C4
InChI
1S/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H
InChI key
WSEFYHOJDVVORU-UHFFFAOYSA-N
应用
An organic photo-catalyst used in synthesis of small molecules as well as polymerization reactions.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Hengbin Wang et al.
Journal of the American Chemical Society, 140(1), 163-166 (2017-12-20)
We describe a new catalytic approach to selective functionalization of the strong C-F bonds in trifluoromethylaromatic (Ar-CF3) systems. In this approach, single electron reduction of Ar-CF3 substrates (using a photoredox catalyst) results in difluorobenzylic radical formation through a C-F cleavage
Single-Ion Homopolymer Electrolytes with High Transference Number Prepared by Click Chemistry and Photoinduced Metal-Free Atom-Transfer Radical Polymerization.
Li. S, et al.
ACS Energy Letters, 3(1), 20-27 (2018)
Honghong Gong et al.
Angewandte Chemie (International ed. in English), 57(1), 333-337 (2017-11-15)
Fluorinated polymers are important materials that are widely used in many areas. Herein, we report the development of a metal-free photocontrolled radical polymerization of semifluorinated (meth)acrylates with a new visible-light-absorbing organocatalyst. This method enabled the production of a variety of
Mao Chen et al.
ACS central science, 3(2), 124-134 (2017-03-11)
Light-initiated additive manufacturing techniques typically rely on layer-by-layer addition or continuous extraction of polymers formed via nonliving, free radical polymerization methods that render the final materials "dead" toward further monomer insertion; the polymer chains within the materials cannot be reactivated
Photocontrolled Growth of Cross-Linked Nanonetworks.
Lampley M W, et al.
ACS Macro Letters, 7(6), 745-750 (2018)
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