推荐产品
表单
liquid
反应适用性
reaction type: C-H Activation
reagent type: catalyst
reagent type: oxidant
折射率
n/D 1.444
密度
1.361 g/mL
InChI
1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
InChI key
ZBIKORITPGTTGI-UHFFFAOYSA-N
应用
橙花醇转化为橙花醛的 TEMPO 氧化反应中的化学计量氧化剂。用作铑催化的烯烃与氨基磺酸酯进行氮杂环丙化反应中的氧化剂。
用于合成各种杂环化合物的试剂。
用于室温下钯催化的吲哚的 2-芳基化反应。
Unactivated sp3 C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)2 as a stoichiometric oxidant.
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产品编号
说明
价格
警示用语：
Warning
危险分类
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Central nervous system
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
S Garadnay et al.
Current medicinal chemistry, 8(6), 621-626 (2001-04-03)
The reactions of morphine and its derivatives with phenyliodo(III)diacetate (PIDA) have been studied. This methodology has not been introduced to morphine alkaloids, despite the fact that such a strategy would ensure dearomatization of the electrophilic aromatic ring of morphine derivatives
Renhua Fan et al.
Organic & biomolecular chemistry, 6(24), 4615-4621 (2008-11-29)
An efficient one-pot oxidative decarboxylation-Friedel-Crafts reaction of acyclic alpha-amino acid derivatives with electron-rich aromatic compounds is reported. The reaction is activated by the combination of iodobenzene diacetate, iodine and iron dust, resulting in a mild and simple reaction system. The
G Wells et al.
Journal of medicinal chemistry, 43(8), 1550-1562 (2000-04-26)
Hydroxylated styrenes (tyrphostins) undergo oxidation by hypervalent iodine oxidants such as [(diacetoxy)iodo]benzene (DAIB) to give a range of products depending on the structure of the phenolic substrate, the solvent, the oxidant stoichiometry, and the purification strategy. Conditions have been developed
Determination of vitamin C in tablets and fruits by titration with phenyliodosoacetate.
S K Vaidya et al.
Il Farmaco; edizione pratica, 37(1), 9-14 (1982-01-01)
Lopa V Desai et al.
Journal of the American Chemical Society, 126(31), 9542-9543 (2004-08-05)
This communication describes a new palladium-catalyzed method for the oxygenation of unactivated sp3 C-H bonds. A wide variety of alkane substrates containing readily available oxime and/or pyridine directing groups are oxidized with extremely high levels of chemo-, regio-, and in
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