form
powder or solid
reaction suitability
reagent type: catalyst
reaction type: Fluorinations
greener alternative product characteristics
Catalysis
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Greener Alternative Product
greener alternative category
, Aligned
storage temp.
2-8°C
Application
Bifluoride salt reported by K. Barry Sharpless and colleagues as a powerful catalyst for the sulfur(VI) fluoride exchange (SuFEx) reaction between aryl silyl ethers and aryl fluorosulfates or alkyl sulfonyl fluorides. Superior to organosuperbases DBU and BEMP, tris(dimethylamino)sulfonium bifluoride enables low catalyst loading (0.05 mol%) for preparation of polysulfates and polysulfonates with high molecular weight and narrow polydispersity. Reaction is amenable to scale up.
General description
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存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Hua Wang et al.
Angewandte Chemie (International ed. in English), 56(37), 11203-11208 (2017-08-10)
The SuFEx-based polycondensation between bisalkylsulfonyl fluorides (AA monomers) and bisphenol bis(t-butyldimethylsilyl) ethers (BB monomers) using [Ph
相关内容
The Sharpless Lab pursues useful new reactivity and general methods for selectively controlling chemical reactions.
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