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Merck
CN
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安全信息

901426

Sigma-Aldrich

Propargyl methacrylate

≥98.0%, contains 200 ppm MEHQ as inhibitor

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About This Item

经验公式（希尔记法）:
C7H8O2
CAS号:
13861-22-8
分子量:
124.14
MDL编号:
MFCD00048123
UNSPSC代码:
12162002

方案

≥98.0%

表单

liquid

颜色

colorless to pale yellow

储存温度

−20°C

InChI

1S/C7H8O2/c1-4-5-9-7(8)6(2)3/h1H,2,5H2,3H3

InChI key

PZAWASVJOPLHCJ-UHFFFAOYSA-N

一般描述

Propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest.

象形图

FlameExclamation mark
GHS02,GHS07

警示用语：

Warning

危险声明

H226,H315,H319

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

120.2 °F

闪点(°C)

49 °C

法规信息

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分析证书(COA)

Lot/Batch Number
MKCG5812

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访问文档库

Self-assembling amphiphilic poly(propargyl methacrylate) grafted DNA copolymers into multi-strand helices
Meng Y F, et al.
Soft Matter, 11, 5610- 513 (2015)
Postfunctionalization of poly(propargyl methacrylate) using copper catalyzed 1,3-dipolar Huisgen cycloaddition: An easy route to electro-optic materials
Scarpaci A. et al.
Journal of Polymer Science: Part A, General Papers, 47, 5652- 560 (2009)
Clickable and Antifouling Platform of Poly[(propargyl methacrylate)-ran-(2-methacryloyloxyethyl phosphorylcholine)] for Biosensing Applications
Wiarachai O, et al.
Langmuir, 32 (4), 1184-1194 (2016)
Jincai Wang et al.
Journal of chromatography. A, 1628, 461481-461481 (2020-08-22)
A single-step copolymerization strategy was developed for the preparation of carbohydrate (glucose and maltose) functionalized monoliths using click reaction. Firstly, novel carbohydrate-functionalized methacrylate monomers were synthesized through Cu(I)-catalyzed 1,3-dipolar cycloaddition (alkyne-azide reaction) of terminal alkyne with azide of carbohydrate derivatives.

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