901272
Dodeca(2,3,4,5,6-pentafluorobenzyloxy)-hypercloso-dodecaborane
别名:
Dodecaborate clusters, Metal-free photooxidant
SMILES string
FC1=C(F)C(F)=C(F)C(F)=C1COB2B(OCC3=C(F)C(F)=C(F)C(F)=C3F)B(OCC4=C(F)C(F)=C(F)C(F)=C4F)B5(OCC6=C(F)C(F)=C(F)C(F)=C6F)B(OCC7=C(F)C(F)=C(F)C(F)=C7F)[B@](B(OCC8=C(F)C(F)=C(F)C(F)=C8F)B(OCC9=C(F)C(F)=C(F)C(F)=C9F)B(OCC%10=C(F)C(F)=C(F)C(F)=C%10F)B5OCC%11=C(F)C
form
powder
Application
Icosahedral dodecaborate clusters of the type B12(OCH2C6F5)12 are new class of metal-free photooxidants able to undergo photoexcitation with visible light. These clusters have been utilized for the oxidation of both activated and unactivated olefins in the presence of blue light, leading to their polymerization.
Legal Information
Sold under Material Transfer Agreement with Prof. Alexander Spokoyny from Department of Chemistry and Biochemistry, UCLA.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Alex I Wixtrom et al.
Inorganic chemistry frontiers, 3(5), 711-717 (2016-11-26)
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the
Marco S Messina et al.
Journal of the American Chemical Society, 138(22), 6952-6955 (2016-05-18)
We report a discovery that perfunctionalized icosahedral dodecaborate clusters of the type B12(OCH2Ar)12 (Ar = Ph or C6F5) can undergo photo-excitation with visible light, leading to a new class of metal-free photooxidants. Excitation in these species occurs as a result
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