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表单
powder
SMILES字符串
FC1=C(F)C(F)=C(F)C(F)=C1COB2B(OCC3=C(F)C(F)=C(F)C(F)=C3F)B(OCC4=C(F)C(F)=C(F)C(F)=C4F)B5(OCC6=C(F)C(F)=C(F)C(F)=C6F)B(OCC7=C(F)C(F)=C(F)C(F)=C7F)[B@](B(OCC8=C(F)C(F)=C(F)C(F)=C8F)B(OCC9=C(F)C(F)=C(F)C(F)=C9F)B(OCC%10=C(F)C(F)=C(F)C(F)=C%10F)B5OCC%11=C(F)C
应用
Icosahedral dodecaborate clusters of the type B12(OCH2C6F5)12 are new class of metal-free photooxidants able to undergo photoexcitation with visible light. These clusters have been utilized for the oxidation of both activated and unactivated olefins in the presence of blue light, leading to their polymerization.
法律信息
Sold under Material Transfer Agreement with Prof. Alexander Spokoyny from Department of Chemistry and Biochemistry, UCLA.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Marco S Messina et al.
Journal of the American Chemical Society, 138(22), 6952-6955 (2016-05-18)
We report a discovery that perfunctionalized icosahedral dodecaborate clusters of the type B12(OCH2Ar)12 (Ar = Ph or C6F5) can undergo photo-excitation with visible light, leading to a new class of metal-free photooxidants. Excitation in these species occurs as a result
Alex I Wixtrom et al.
Inorganic chemistry frontiers, 3(5), 711-717 (2016-11-26)
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the
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