901267
Hexamethylborazine
≥95%
别名:
1,2,3,4,5,6-Hexamethyl-1,3,5,2,4,6-triazatriborinane
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关于此项目
经验公式（希尔记法）:
C6H18B3N3
化学文摘社编号:
分子量:
164.66
UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
SMILES string
B1(N(B(N(B(N1C)C)C)C)C)C
InChI
1S/C6H18B3N3/c1-7-10(4)8(2)12(6)9(3)11(7)5/h1-6H3
InChI key
LCHQMXUQYONIOI-UHFFFAOYSA-N
assay
≥95%
form
powder or crystals
reaction suitability
core: boron, reagent type: catalyst
mp
99 °C
storage temp.
−20°C
Quality Level
Application
Hexamethylborazine has been developed by the Szymczak lab for the delivery of alkyl and hydride nucleophiles in addition to being a key component in the synthesis of recyclable trifluoromethylation reagents.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Borazine?CF3? Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation.
Geri J B, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 130(5), 1395-1399 (2018)
Reduction of Borazines Mediated by Low?Valent Chromium Species.
Carter T J, et al.
Angewandte Chemie (International Edition in English), 51(52), 13168-13172 (2012)
Manganese-Mediated Hydride Delivery to a Borazine by Stepwise Reduction and Protonation.
Carter T J, et al.
Organometallics, 33(7), 1540-1543 (2014)
Recyclable Trifluoromethylation Reagents from Fluoroform.
Geri J B and Szymczak N K
Journal of the American Chemical Society, 139(29), 9811-9814 (2017)
Manganese-mediated hydride delivery to a borazine by stepwise reduction and protonation.
Carter TJ, et al.
Organometallics, 33 (7), 1540-1543 (2014)
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