检测方案
≥95%
形式
powder or crystals
反应适用性
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation
mp
142 °C
应用
(S)-Ph-quinox is a chiral dinitrogen ligand which is used in the iridium-catalyzed enantioselective borylation and silylation of aromatic C-H bonds, in addition to the enantioselective palladium-catalyzed diamination of alkenes. It can also be used in the aza-Wacker-type cyclization reaction of the olefinic tosylamides with molecular oxygen.
相关产品
产品编号
说明
价格
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Enantioselective Borylation of Aromatic C? H Bonds with Chiral Dinitrogen Ligands.
Su B, et al.
Angewandte Chemie (International Edition in English), 56(25), 7205-7208 (2017)
Pd-catalyzed asymmetric aza-Wacker-type cyclization reaction of olefinic tosylamides.
Jiang F, et al.
Tetrahedron Letters, 51(39), 5124-5126 (2010)
A Chiral Nitrogen Ligand for Enantioselective, Iridium?Catalyzed Silylation of Aromatic C? H Bonds.
Su B, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 129(4), 1112-1116 (2017)
Erica L Ingalls et al.
Journal of the American Chemical Society, 135(24), 8854-8856 (2013-06-06)
An enantioselective Pd-catalyzed vicinal diamination of unactivated alkenes using N-fluorobenzenesulfonimide as both an oxidant and a source of nitrogen is reported. The use of Ph-pybox and Ph-quinox ligands afforded differentially protected vicinal diamines in good yields with high enantioselectivities. Mechanistic
商品
QuinoxP*: Air-Stable and Highly Efficient and Productive Chiral Ligands
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