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901116

Sigma-Aldrich

反式-双（二环己基苯基膦）（2-甲基苯基）氯化镍（II）

别名:

反式-(PCy2Ph)2Ni(o-甲苯基)Cl

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About This Item

经验公式（希尔记法）:
C43H61ClNiP2
CAS号:
1419179-26-2
分子量:
734.04
UNSPSC代码:
12352200

表单

powder or solid

反应适用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

174-179 °C

SMILES字符串

Cl[Ni](P(C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C3([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C3([H])[H])(P(C4([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C4([H])[H])(C5=C([H])C([H])=C([H

其他说明

法律信息

专利申请 PCT/US2014/064565。经麻省理工学院许可销售。

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
MKCF3680

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Recent advances in homogeneous nickel catalysis.
Tasker S Z
Nature, 509(7500), 299-299 (2014)
Simplifying nickel (0) catalysis: an air-stable nickel precatalyst for the internally selective benzylation of terminal alkenes.
Standley E A and Jamison T F
Journal of the American Chemical Society, 135(4), 1585-1592 (2013)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.

商品

Jamison Nickel (II) Precatalysts

The Jamison group has developed a library of bench-stable phosphine-containing nickel(II) precatalysts that are converted into active catalysts in situ.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

相关内容

Jamison Group – Professor Product Portal

Jamison group focuses on new reaction development for organic synthesis, pioneering air-stable nickel precatalysts.

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