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Merck
CN

901116

反式-双(二环己基苯基膦)(2-甲基苯基)氯化镍(II)

别名:

反式-(PCy2Ph)2Ni(o-甲苯基)Cl

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关于此项目

经验公式(希尔记法):
C43H61ClNiP2
化学文摘社编号:
分子量:
734.04
UNSPSC Code:
12352200
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SMILES string

Cl[Ni](P(C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C3([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C3([H])[H])(P(C4([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C4([H])[H])(C5=C([H])C([H])=C([H

form

powder or solid

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

mp

174-179 °C

Legal Information

专利申请 PCT/US2014/064565。经麻省理工学院许可销售。

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

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Simplifying nickel (0) catalysis: an air-stable nickel precatalyst for the internally selective benzylation of terminal alkenes.
Standley E A and Jamison T F
Journal of the American Chemical Society, 135(4), 1585-1592 (2013)
Recent advances in homogeneous nickel catalysis.
Tasker S Z
Nature, 509(7500), 299-299 (2014)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.

商品

The Jamison group has developed a library of bench-stable phosphine-containing nickel(II) precatalysts that are converted into active catalysts in situ.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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Jamison group focuses on new reaction development for organic synthesis, pioneering air-stable nickel precatalysts.

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