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Merck
CN

901099

PBDB-T

greener alternative

别名:

聚[[4,8-双[5-(2-乙基己基)-2-噻吩基]苯并[1,2-b:4,5-b′]二噻吩-2,6-二基]-2,5-噻吩二基[ 5,7-双(2-乙基己基)-4H,8H-二氧代-4H,8H-苯并[1,2-c:4,5-c′]二噻吩-1,3-二基]]聚合物

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关于此项目

线性分子式:
(C68H78O2S8)n
化学文摘社编号:
1415929-80-4
MDL number:
MFCD00133992
NACRES:
NA.23
UNSPSC Code:
12162002

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description

Band gap: 1.8 eV
Limited solubility in CHCl3

form

powder

mol wt

Mw >50,000 by GPC (GPC standard: PS)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>200 °C

solubility

chlorobenzene: soluble
dichlorobenzene: soluble

orbital energy

HOMO -5.28 eV 
LUMO -3.48 eV 

PDI

<3.0

greener alternative category

, Enabling

Quality Level

100

相关类别

Application

PBDB-T 是一种共轭推挽中等带隙聚合物供体，可用作用于聚合物太阳能电池（PSC）的供体分子。它还可用于制造有机薄膜晶体管（OTFT）。

General description

我们致力于为您带来更加绿色的替代产品，这些产品遵守一项或多项绿色化学12项原则。本品属于绿色替代产品的赋能型产品，符合“节能设计”原则。空穴传输有机材料与吸收层的能级排列完美匹配，因此实现高效的电荷收集，它在环境条件下易于降解。点击此处 了解更多信息。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT3550
MKCS4489
MKCP6515
MKCF2708

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Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells.
Li S, et al.
Advanced Materials, 28(42), 9423-9429 (2016)
Reducing the confinement of PBDB-T to ITIC to improve the crystallinity of PBDB-T/ITIC blends
Liang Q, et al.
Journal of Material Chemistry A, 6(32), 15610-15620 (2018)
Wenchao Zhao et al.
Advanced materials (Deerfield Beach, Fla.), 29(2) (2016-11-05)
Ternary polymer solar cells are fabricated based on one donor PBDB-T and two acceptors (a methyl-modified small-molecular acceptor (IT-M) and a bis-adduct of Bis[70]PCBM). A high power conversion efficiency of 12.2% can be achieved. The photovoltaic performance of the ternary
Effect of dihydronaphthyl-based C60 bisadduct as third component materials on the photovoltaic performance and charge carrier recombination of binary PBDB-T: ITIC polymer solar cells
Niu S, et al.
Nanoscale, 10(18), 8483-8495 (2018)
The influence of air and temperature on the performance of PBDB-T and P3HT in organic thin film transistors
Brixi S, et al.
Journal of Material Chemistry C, 6(44), 11972-11979 (2018)
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