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Merck
CN
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安全信息

900941

Sigma-Aldrich

氯(4-氰基苯基)[(R)-1-[(S)-2-[双(4-氟苯基]膦基]二茂铁基]乙基二-叔-丁基膦]镍(II)

≥95%

别名:

SK-J014-1n

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About This Item

经验公式（希尔记法）:
C39H42ClF2FeNNiP2
CAS号:
2049086-37-3
分子量:
774.69
MDL编号:
MFCD31619172
UNSPSC代码:
12352103
NACRES:
NA.22

质量水平

100

方案

≥95%

表单

powder or solid

反应适用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

SMILES字符串

CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=C(F)C=C2)C3=CC=C(F)C=C3.Cl[Ni]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]

相关类别

应用

Amination of functionalized aryl chlorides with ammonia and ammonium salts.

警示用语：

Warning

危险声明

H315,H361d,H411

危险分类

Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCM9788
MKCF1834

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Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Green R A and Hartwig J F
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.

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