900268
双（3,5-双（三氟甲基）苯基）(2′,6′-双（异丙氧基）-3,6-二甲氧基联苯-2-基）膦
≥95%, powder or crystals
别名:
2- {双[3,5-双（三氟甲基）苯基]膦基} -3,6-二甲氧基-2′,6′-双（异丙氧基）-1,1′-联苯
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关于此项目
经验公式（希尔记法）:
C36H31F12O4P
化学文摘社编号:
分子量:
786.58
UNSPSC Code:
12352200
PubChem Substance ID:
产品名称
双（3,5-双（三氟甲基）苯基）(2′,6′-双（异丙氧基）-3,6-二甲氧基联苯-2-基）膦, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reagent type: ligand
reaction type: Cross Couplings
functional group
phosphine
Application
双（3,5-双（三氟甲基）苯基）（2′,6′-双（异丙氧基）-3,6-二甲氧基联苯-2-基）膦是来自Buchwald</A族的Pd-G4络合物，其在空间位阻二级胺的芳基化反应中具有同类中最佳的性能。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Nathaniel H Park et al.
Angewandte Chemie (International ed. in English), 54(28), 8259-8262 (2015-06-03)
In Pd-catalyzed C-N cross-coupling reactions, α-branched secondary amines are difficult coupling partners and the desired products are often produced in low yields. In order to provide a robust method for accessing N-aryl α-branched tertiary amines, new catalysts have been designed
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