蒸汽密度
6.8 (vs air)
质量水平
检测方案
≥97.0% (GC)
形式
liquid
自燃温度
455 °F
折射率
n20/D 1.436 (lit.)
n20/D 1.436
bp
251 °C (lit.)
mp
−13-−11 °C (lit.)
密度
0.775 g/mL at 25 °C (lit.)
SMILES字符串
CCCCCCCCCCCCC=C
InChI
1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
InChI key
HFDVRLIODXPAHB-UHFFFAOYSA-N
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应用
1-Tetradecene can be used as a reactant to synthesize:
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
- 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
- (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
警示用语:
Danger
危险声明
危险分类
Asp. Tox. 1
补充剂危害
WGK
WGK 3
闪点(°F)
230.0 °F
闪点(°C)
110 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of methyl ketones from terminal olefins using PdCl2/CrO3 system mimicking the Wacker process
Tetrahedron, 70(32), 4760-4767 (2014)
Diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid
Tetrahedron Asymmetry, 23(1), 60-66 (2012)
Synthesis of ultrahigh molecular weight polymers with low PDIs by polymerizations of 1-decene, 1-dodecene, and 1-tetradecene by Cp* TiMe2 (O-2, 6-iPr2C6H3)-borate catalyst
Molecules (Basel), 24(8), 1634-1634 (2019)
Cell and tissue banking, 16(4), 631-638 (2015-07-15)
Increasingly dental surgeons face the challenge of reconstruction of the height and/or thickness of the alveolar ridge as more and more patients wish to have permanent restoration of their dental defects based on intraosseous implants. Evaluation of human allogeneic bone
The journal of physical chemistry. B, 118(49), 14140-14147 (2014-08-27)
Quantum dots (QDs) offer distinct advantages over organic dyes and fluorescent proteins for biological imaging applications because of their brightness, photostability, and tunability. However, a major limitation is that single QDs emit fluorescent light in an intermittent on-and-off fashion called
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