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About This Item
线性分子式:
(CH3CH2CH2CH2)4N(OCOCH3)
CAS号:
分子量:
301.51
Beilstein:
3599376
EC 号:
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
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一般描述
Tetrabutylammonium acetate is an effective alternative for sodium acetate (NaOAc) due to its good solubility in organic solvents.
应用
Tetrabutylammonium acetate (TBAAc) is a good source of nucleophilic acetate ion for SN2 substitution reactions. It is commonly used to displace sulfonates and allylic halides to get corresponding acetates. Additionally, TBAAc can also be used as a mild, soluble base in Sonogashira reaction and Heck arylation.
其他说明
用于羟基差向异构化的试剂；引导 Heck 型反应的碱性熔融盐
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Tetrabutylammonium Acetate.
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Secondary deuterium kinetic isotope effects and the intervention of nonclassical ions in the solvolysis of exo-norborn-2-yl bromobenzene-p-sulfonate.
Maskill H,
Journal of the American Chemical Society, 98(26), 8482-8485 (1976)
T. Jeffery, M. David
Tetrahedron Letters, 39, 5751-5751 (1998)
Pd nanoparticle catalyzed Heck arylation of 1, 1-disubstituted alkenes in ionic liquids. Study on factors affecting the regioselectivity of the coupling process.
Calo V, et al.
Organometallics, 22(21), 4193-4197 (2003)
T. Jeffery
Tetrahedron Letters, 40, 1673-1673 (1999)
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