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表单
liquid
质量水平
反应适用性
core: titanium
reagent type: catalyst
杂质
≤3% tetraisopropyl orthotitanate (NMR)
折射率
n20/D 1.505 (lit.)
n20/D 1.509
沸点
150-152 °C/10 mmHg (lit.)
密度
1.088 g/mL at 25 °C (lit.)
SMILES字符串
CCO[Ti](OCC)(OCC)OCC
InChI
1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
InChI key
JMXKSZRRTHPKDL-UHFFFAOYSA-N
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应用
乙醇钛(IV)可用于:
- 作为活化剂和脱水剂,通过(S)-(+)-p-甲苯磺酰胺与醛和酮的缩合,形成亚磺酰亚胺。
- 作为Ti4+ 离子源形成丙烯酸钛(Ⅳ)与甲基丙烯酸的配合物。
- 作为催化剂,通过酯交换反应合成位阻醇酯。
注意
在储存期间,会形成凝胶状残余物,在加热至40℃后可溶解
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
107.6 °F - closed cup
闪点(°C)
42 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of sterically hindered esters via titanium catalyzed transesterification
Tetrahedron Letters, 39(24), 4223-4226 (1998)
Two-photon polymerization of metal ions doped acrylate monomers and oligomers for three-dimensional structure fabrication
Thin Solid Films, 453(4), 518-521 (2004)
Improved synthesis of enantiopure sulfinimines (thiooxime s-oxides) from p-toluenesulfinamide and aldehydes and ketones
The Journal of Organic Chemistry, 64(4), 1403-1406 (1999)
Journal of colloid and interface science, 435, 51-58 (2014-09-14)
Ag/TiO2 nanocomposites were prepared through combination of a sol-gel process of a titanium precursor in inverse miniemulsions and in situ reduction of silver ions in the "nanoreactors". The morphological investigation shows that Ag nanoparticles are mainly located on the surface
International journal of nanomedicine, 10, 4425-4436 (2015-07-18)
The osseointegration capacity of bone-anchoring implants can be improved by the use of drugs that are administrated by an inbuilt drug delivery system. However, to attain superior control of drug delivery and to have the ability to administer drugs of
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