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Merck
CN

86652

Sigma-Aldrich

四乙基高碘酸铵

technical, moistened with water, ≥90% (calc. based on dry substance, RT)

别名:

N,N,N-Triethylethanaminium salt with periodic acid

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About This Item

线性分子式:
(C2H5)4N(IO4)
CAS号:
分子量:
321.15
Beilstein:
4166132
EC 号:
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
NACRES:
NA.22

等级

technical

方案

≥90% (calc. based on dry substance, RT)

表单

crystals

质量

moistened with water

包含

~10% water as stabilizer

反应适用性

reagent type: oxidant

mp

~170 °C (dec.)

SMILES字符串

[O-]I(=O)(=O)=O.CC[N+](CC)(CC)CC

InChI

1S/C8H20N.HIO4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

YXYPONURGKGPDV-UHFFFAOYSA-M

应用

Reactant for intramolecular cycloaddition reactions
Tetraethylammonium (meta)periodate can be used as an oxidant in the N-dealkylation of tertiary amines using Fe(III) complex as a catalyst. It can also be employed as a reagent in the intramolecular cycloaddition reactions.

其他说明

在有机溶剂中使用的氧化剂;1,2-二醇和烯烃类化合物的氧化

象形图

Flame

警示用语:

Danger

危险声明

预防措施声明

危险分类

Flam. Sol. 1

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

A.A. Freer et al.
Journal of the Chemical Society. Perkin Transactions 1, 1001-1001 (1991)
G.E. Keck
Tetrahedron Letters, 4767-4767 (1978)
Oxidative N-Dealkylation of Tertiary Amines with Tetraethylammonium Periodate Catalyzed by Metal Complexes
Bhat, Daisy and Sharma, Nidhi
Australian Journal of Chemistry, 70(3), 233-236 (2017)
Synthesis of (2R, 5R)-2-amino-5-hydroxyhexanoic acid by intramolecular cycloaddition
Sheradsky T and Silcoff ER
Molecules (Basel), 3(3), 80-87 (1998)
K. Inomata et al.
Bulletin of the Chemical Society of Japan, 53, 565-565 (1980)

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