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Merck
CN

86142

Sigma-Aldrich

4-磺酰杯[4]芳烃 钠盐

≥95.0% (HPLC)

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别名:
25,26,27,28-四羟基杯[4]芳烃-5,11,17,23-四磺酸 钠盐, 四羟基杯[4]芳烃四磺酸 钠盐
线性分子式:
C28H24-xO16S4Nax
Beilstein:
5221495
UNSPSC代码:
12350000
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥95.0% (HPLC)

形式

crystals

杂质

≤3% methanol

mp

≥300 °C (lit.)

SMILES字符串

[Na].Oc1c2Cc3cc(cc(Cc4cc(cc(Cc5cc(cc(Cc1cc(c2)S(O)(=O)=O)c5O)S(O)(=O)=O)c4O)S(O)(=O)=O)c3O)S(O)(=O)=O

InChI

1S/C28H24O16S4.Na/c29-25-13-1-14-6-22(46(36,37)38)8-16(26(14)30)3-18-10-24(48(42,43)44)12-20(28(18)32)4-19-11-23(47(39,40)41)9-17(27(19)31)2-15(25)7-21(5-13)45(33,34)35;/h5-12,29-32H,1-4H2,(H,33,34,35)(H,36,37,38)(H,39,40,41)(H,42,43,44);/q;+1/p-1

InChI key

GZPNIEYNWYONCE-UHFFFAOYSA-M

一般描述

4-Sulfocalix[4]arene is a cyclic oligomer, which is prepared by hydroxyalkylation of phenol and aldehyde. It belongs to the family of calixarenes with repeating phenolic units connected via methylene groups forming a macrocyclic molecule. It has an amphiphilic nature with different functional groups that make it useful in drug delivery systems. It shows potential applications in various fields such as analysis and separation, enzyme mimetic systems and self-assembly membranes.

应用

4-Sulfocalix[4]arene sodium salt is an amphiphilic calix[n]arene that can be used as a coupling agent for organic molecules and metal complexes because of its hydrophobic (aromatic ring) and hydrophilic (SO3-) environments.

其他说明

水溶性杯芳烃;络合剂,例如用于镧系元素;区域选择性酸催化剂

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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N. Sato et al.
Chemistry Letters (Jpn), 1261-1261 (1993)
Lateral assembly of oxidized graphene flakes into large-scale transparent conductive thin films with a three-dimensional surfactant 4-sulfocalix [4] arene
Sundramoorthy AK, et al.
Scientific reports, 5, 10716-10716 (2015)
M. Komiyama et al.
Chemistry Letters (Jpn), 937-937 (1991)
I. Yoshida et al.
Chemistry Letters (Jpn), 2105-2105 (1991)
Binding of Ru (NH3) 5pz2+ to 4-Sulfocalix [4] arene Sodium Salt. Effects of the Host- Guest Interaction on Electron Transfer Processes
Lopez-Cornejo P, et al.
The Journal of Physical Chemistry B, 113(38), 12721-12726 (2009)

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