形式
solid
质量水平
组成
FeCl2 (372870), 23.3-27.4 wt. %
MgCl2 (M8266), 15.3-18.8 wt. %
Pd (203939), <0.3 wt. %
THF (186562), 53.5-61.6 wt. %
反应适用性
core: iron
reagent type: catalyst
储存温度
2-8°C
应用
When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.
注意
Handle under nitrogen and store under argon in refrigerator.
其他说明
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead
From milligrams to kilograms: synthetic chemistry following nature′s lead
相关产品
产品编号
说明
价格
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
1.4 °F
闪点(°C)
-17 °C
法规信息
危险化学品
When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)
New surfactants for chemistry in water.
Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
Switching from organic solvents to water at an industrial scale.
Current opinion in green and sustainable chemistry., 7, 13-17 (2017)
相关内容
Prof. Bruce Lipshutz and co-workers have developed designer surfactants to allow several classes of transformations (e.g. Suzuki-Miyaura, Olefin Metathesis, 1,4-Addition to Enones, etc.) to be performed in water.
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