推荐产品
表单
liquid
折射率
n/D 1.510
密度
1.126 g/mL
储存温度
2-8°C
SMILES字符串
O=C(N(OC)C)N1C=CC=C1
InChI
1S/C7H10N2O2/c1-8(11-2)7(10)9-5-3-4-6-9/h3-6H,1-2H3
InChI key
NLSJGNBOCVXWHS-UHFFFAOYSA-N
应用
The CLAmP (Carbonyl Linchpin N, O-dimethylhydroxylamine pyrrole) reagent, reported by Sarpong and Heller, is a useful building block for the efficient synthesis of unsymmetrical ketones. CLAmP shows high versatility based on compatibility with both highly reactive, thermally unstable nucleophiles as well as less reactive stable nucleophiles. It reacts with Grignard reagents to form the corresponding Weinreb amides.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
230.0 °F
闪点(°C)
110 °C
法规信息
新产品
One-pot Unsymmetrical Ketone Synthesis Employing a Pyrrole-Bearing Formal Carbonyl Dication Linchpin Reagent.
Angewandte Chemie (International Edition in English), 54(34), 9839-9843 (2015)
相关内容
Professor Heller's research focuses on mild acylation reactions using carbonylimidazole-derived reagents.
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