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Merck
CN

806501

Sigma-Aldrich

Boc-Thr(tBu)-OH

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别名:
N-叔丁氧羰基-O-叔丁基-L-苏氨酸
线性分子式:
(CH3)3COCH(CH3)CH(COOH)NHCOOC(CH3)3
CAS号:
分子量:
275.34
Beilstein:
4454820
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22

检测方案

95%

质量水平

形式

powder

mp

98.9 °C

应用

peptide synthesis

储存温度

2-8°C

SMILES字符串

C[C@@H](OC(C)(C)C)[C@H](NC(=O)OC(C)(C)C)C(O)=O

InChI

1S/C13H25NO5/c1-8(18-12(2,3)4)9(10(15)16)14-11(17)19-13(5,6)7/h8-9H,1-7H3,(H,14,17)(H,15,16)/t8-,9+/m1/s1

InChI key

LKRXXARJBFBMCE-BDAKNGLRSA-N

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一般描述

Boc-Thr(t-Bu)-OH (N-Boc-O-tert-butyl-L-threonine) participates in the synthesis of 2,3-unsaturated glycosides, via reaction with per-O-acetylated glucal in the presence of Er(OTf)3 catalyst.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Antonio Procopio et al.
Carbohydrate research, 342(14), 2125-2131 (2007-06-23)
Er(OTf)(3) is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transformation has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be
Christian Haenig et al.
Cell reports, 32(7), 108050-108050 (2020-08-20)
Interactome maps are valuable resources to elucidate protein function and disease mechanisms. Here, we report on an interactome map that focuses on neurodegenerative disease (ND), connects ∼5,000 human proteins via ∼30,000 candidate interactions and is generated by systematic yeast two-hybrid

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