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804975

DTBPF-Pd-G3

Name: DTBPF-Pd-G3
Brand: ALDRICH

别名:

1,1′-Bis(di-tert-butylphosphino)ferrocene Pd G3

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About This Item

经验公式（希尔记法）:

C₃₉H₅₇FeNO₃P₂PdS

分子量:

844.15

MDL编号:

MFCD28009169

UNSPSC代码:

12352103

PubChem化学物质编号:

329768913

NACRES:

NA.22

形式

solid

质量水平

100

特点

generation 3

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

杂质

may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number 762156)
may contain 5-10% DTBPF (Aldrich Number 695149)
may contain 5-10% pentane

mp

87-150 °C (decomposition)

官能团

phosphine

InChI

1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1

InChI key

AGXLTHQKOWPGBX-UHFFFAOYSA-M

一般描述

DTBPF-Pd-G-3 is a versatile palladium precatalyst developed by Buchwald group. It is widely employed in various cross-coupling reactions involving the formation of C-C, C-N, C-O, C-F, C-CF₃, and C-S bonds. Precatalysts effectively generate active catalytic species for use in various reactions.

应用

Pd precatalyst for cross-coupling. Buchwald Third Generation Palladium Precatalyst.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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