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804959

DavePhos-Pd-G3

Name: DavePhos-Pd-G3
Brand: ALDRICH
Price: 5282.92 CNY

95%

别名:

甲烷磺酸-2-二环己基膦基-2-(N,N-二甲胺基)联苯基(′-氨基-1,1′-联苯-2-基)钯(II)

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1 KIT

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CN¥5,282.92

About This Item

经验公式（希尔记法）:

C₃₉H₄₉N₂O₃PPdS

CAS号:

1445085-87-9

分子量:

763.28

MDL编号:

MFCD27978422

UNSPSC代码:

12161600

PubChem化学物质编号:

329768911

NACRES:

NA.22

CN¥5,282.92

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2-二环己膦基-2′-(N,N-二甲胺)联苯

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900702

DavePhos Pd G4

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763004

CPhos Pd G3

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RuPhos Pd G3

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tBuDavePhos Pd G3

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JackiePhos Pd G3

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XantPhos Pd G3

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BrettPhos Pd G3

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Pd-PEPPSI^™-IPent催化剂

Sigma-Aldrich

669032

PEPPSI^™-IPr 催化剂

质量水平

100

方案

95%

表单

solid

特点

generation 3

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

杂质

<5% THF

mp

183-200 °C (decomp)

官能团

phosphine

SMILES字符串

CN(C)C1=C(C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2)C=CC=C1.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5

InChI

1S/C26H36NP.C12H10N.CH4O3S.Pd/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12,17-22H,3-8,13-16H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

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此商品	RAB0469	RAB0473	RAB0467
RAB0468 小鼠 TIMP-1 ELISA 试剂盒	RAB0469 小鼠 TIMP-1 ELISA 试剂盒	RAB0473 小鼠 TIMP-2 ELISA 试剂盒	RAB0467 人类 TIMP-1 ELISA 试剂盒
Gene Information mouse ... Timp1(21857)	Gene Information mouse ... Timp1(21857)	Gene Information mouse ... Timp2(21858)	Gene Information human ... TIMP1(7076)
species reactivity mouse	species reactivity mouse	species reactivity mouse	species reactivity human
assay range inter-assay cv: <12% intra-assay cv: <10% sensitivity: 3 pg/mL standard curve range: 1.37-1000 pg/mL	assay range inter-assay cv: <12% intra-assay cv: <10% sensitivity: 3 pg/mL standard curve range: 1.37-1000 pg/mL	assay range inter-assay cv: <12% intra-assay cv: <10% sensitivity: 80 pg/mL standard curve range: 0.0823-60 ng/mL	assay range inter-assay cv: <12% intra-assay cv: <10% sensitivity: 30 pg/mL standard curve range: 24.69-18000 pg/mL
input sample type cell culture supernatant(s) sample type plasma sample type serum	input sample type cell lysate sample type tissue lysate	input sample type cell culture supernatant(s) sample type plasma sample type serum	input sample type tissue lysate sample type cell lysate
technique(s) ELISA: suitable, capture ELISA: suitable	technique(s) ELISA: suitable, capture ELISA: suitable	technique(s) ELISA: suitable, capture ELISA: suitable	technique(s) ELISA: suitable, capture ELISA: suitable
storage temp. −20°C	storage temp. −20°C	storage temp. −20°C	storage temp. −20°C

一般描述

DavePhos-Pd-G3是经过修饰的G3预催化剂（G3′）。Buchwald及其同事采用第二代（G2）预催化剂通过联苯主链上氨基的甲基化作用合成了它。它是各种交叉偶联反应的催化剂。它们是多功能的催化剂。它们在溶液中的使用寿命很长，并且易溶于各种有机溶剂。G3预催化剂已被用于各种C-N键形成反应。[1]