所有图片(1)
About This Item
经验公式（希尔记法）:
C24H22N2O6S2
分子量:
498.57
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
powder
反应适用性
core: nickel
reagent type: catalyst
SMILES字符串
O=C(N([C@H](C(C=CC=C1)=C1C2)[C@H]2C3)S3(=O)=O)/C=C/C(N4[C@H](C(C=CC=C5)=C5C6)[C@H]6CS4(=O)=O)=O
InChI
1S/C24H22N2O6S2/c27-21(25-23-17(13-33(25,29)30)11-15-5-1-3-7-19(15)23)9-10-22(28)26-24-18(14-34(26,31)32)12-16-6-2-4-8-20(16)24/h1-10,17-18,23-24H,11-14H2/b10-9+/t17-,18-,23+,24+/m1/s1
InChI key
CZVFUQRTDAQUQL-SKLQJEMHSA-N
应用
Enables the generation of quaternary centers by Ni-catalyzed cross coupling with aziridines.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Chung-Yang Dennis Huang et al.
Journal of the American Chemical Society, 137(17), 5638-5641 (2015-04-17)
A Ni-catalyzed Negishi cross-coupling with 1,1-disubstituted styrenyl aziridines has been developed. This method delivers valuable β-substituted phenethylamines via a challenging reductive elimination that affords a quaternary carbon. A novel electron-deficient olefin ligand, Fro-DO, proved crucial for achieving high rates and
相关内容
Doyle group focuses on nucleophilic fluorination using PyFluor and nickel catalysis with modular, air-stable nickel precatalyst.
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