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Merck
CN

804010

Sigma-Aldrich

Co(salen,t-Bu, t-Bu)Cl

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About This Item

经验公式(希尔记法):
C36H52ClCoN2O2
分子量:
639.20
UNSPSC代码:
12352300
PubChem化学物质编号:

表单

powder

反应适用性

reagent type: catalyst
core: cobalt

mp

250 °C

储存温度

2-8°C

SMILES字符串

Cl[Co]1OC(C(C(C)(C)C)=CC(C(C)(C)C)=C2)=C2/C=N/[C@](CCCC3)([H])[C@@]3([H])/N=C/C(C=C(C(C)(C)C)C=C4C(C)(C)C)=C4O1

InChI

1S/C36H54N2O2.ClH.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1

InChI key

DIPYCKRNYQWVPM-RUIQGICGSA-K

应用

When utilized with organosilanes, catalytic amounts of Co(salen,t-Bu, t-Bu)Cl effects the isomerization of terminal alkenes.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Steven W M Crossley et al.
Journal of the American Chemical Society, 136(48), 16788-16791 (2014-11-15)
Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.

相关内容

Shenvi lab repurposed Jacobsen’s cobalt chloride complex for positional isomerization of terminal alkenes via reversible hydrogen atom transfer.

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