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Merck
CN
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安全信息

797294

Sigma-Aldrich

1,1,2,3,4,5-六苯基-1H-噻咯

别名:

1,1,2,3,4,5-六苯基甲硅烷基, 1,1,2,3,4,5-六苯基硅杂环戊-2,4-二烯, 1,1,2,3,4,5-六苯基硅杂环戊二烯, HPS, 六苯基硅杂环戊-2,4-二烯, 六苯基硅环戊二烯

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About This Item

经验公式（希尔记法）:
C40H30Si
CAS号:
752-28-3
分子量:
538.75
MDL编号:
MFCD27976827
UNSPSC代码:
12352103
PubChem化学物质编号:
329768582
NACRES:
NA.23

方案

98%

表单

solid

mp

188-193 °C

SMILES字符串

C1(C2=CC=CC=C2)=C(C3=CC=CC=C3)C(C4=CC=CC=C4)=C(C5=CC=CC=C5)[Si]1(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/C40H30Si/c1-7-19-31(20-8-1)37-38(32-21-9-2-10-22-32)40(34-25-13-4-14-26-34)41(35-27-15-5-16-28-35,36-29-17-6-18-30-36)39(37)33-23-11-3-12-24-33/h1-30H

InChI key

QAKMXYFDVPDIPT-UHFFFAOYSA-N

一般描述

HPS 是用于 OLED 发射层的聚集诱导发射（AIE）材料。1,4,5,6,7,7-六苯基-7-硅双环[2.2.1]庚-5-烯-2,3-二羧酸酐（XIb）的光解和热解可能导致六苯基硅环戊二烯的形成。

应用

六苯基硅烷基环戊二烯可与丙烯酸乙酯进行 π4s+π2s 环加成反应，形成双环硅亚庚烯。同一项研究报道了与各种亲双烯体类似的环加成反应。六苯基硅环戊二烯与过苯甲酸的反应生成四苯基呋喃和顺二苯甲酰二苯乙烯。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBX5158V

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Synthesis, Light Emission, Nanoaggregation, and Restricted Intramolecular Rotation of 1,1-Substituted 2,3,4,5-Tetraphenylsiloles
Junwu Chen, Charles C. W. Law, Jacky W. Y. Lam, et al
Chemistry of Materials, 15(7), 1535-1546 (2003)
Photochemical and thermal transformations of 7-silabicyclo[2.2.1]Heptadiene and 7-silabicyclo[2.2.1]heptene systems
Balasubramanian R and George MV
Journal of Organometallic Chemistry null
Symmetry allowed ?4s+?2s additions silacyclopentadienes
Balasubramanian R and George MV
Tetrahedron null
Peracid oxidation and photooxygenation reactions of silacyclopentadienes,
Mahajan MP, et al.
Tetrahedron null
Peracid oxidation and photooxygenation reactions of silacyclopentadienes,
Mahajan MP, et al.
Tetrahedron, 1549-1553 null
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