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安全和法规

795291

Phenofluor ^™溶液

Name: Phenofluor <SUP>™</SUP>溶液
Brand: ALDRICH

0.1 M in toluene

别名:

1,3-Bis(2,6-diisopropylphenyl)-2,2-difluoro-4-imidazoline

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About This Item

经验公式（希尔记法）:

C₂₇H₃₆F₂N₂

分子量:

426.58

MDL编号:

MFCD22377831

UNSPSC代码:

12352101

PubChem化学物质编号:

329768478

NACRES:

NA.22

形式

liquid

质量水平

100

浓度

0.1 M in toluene

密度

0.865 g/mL at 25 °C

储存温度

2-8°C

InChI

1S/C27H36F2N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)30-15-16-31(27(30,28)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3

InChI key

FQXXWTOSPDVNSG-UHFFFAOYSA-N

应用

Facile deoxyfluorination of phenols without preactivation (), along with highly chemoselective deoxyfluorination of highly functionalized late-stage intermediates ().

法律信息

PhenoFluor is a trademark of SciFluor Life Sciences, LLC

900456

AlkylFluor

象形图

GHS02,GHS08,GHS07

警示用语：

Danger

危险声明

H225,H304,H315,H336,H361d,H373,H412

预防措施声明

P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313

危险分类

Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Central nervous system

WGK

WGK 3

闪点(°F)

39.2 °F

闪点(°C)

4 °C

法规信息

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Late-stage deoxyfluorination of alcohols with PhenoFluor.

Filippo Sladojevich et al.

Journal of the American Chemical Society, 135(7), 2470-2473 (2013-02-13)

An operationally simple protocol for the selective deoxyfluorination of structurally complex alcohols is presented. Several fluorinated derivatives of natural products and pharmaceuticals have been prepared to showcase the potential of the method for late-stage diversification and its functional group compatibility.

Deoxyfluorination of phenols.

Pingping Tang et al.

Journal of the American Chemical Society, 133(30), 11482-11484 (2011-07-09)

An operationally simple ipso fluorination of phenols with a new deoxyfluorination reagent is presented.

商品

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor^™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

文件

安全信息

Phenofluor ^™溶液