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经验公式(希尔记法):
CuI
化学文摘社编号:
分子量:
190.45
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-674-6
MDL number:
Assay:
99.995% trace metals basis
Grade:
anhydrous
Form:
powder
产品名称
碘化亚铜, 99.995% trace metals basis
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
InChI
1S/Cu.HI/h;1H/q+1;/p-1
SMILES string
[Cu+].[I-]
grade
anhydrous
vapor pressure
10 mmHg ( 656 °C)
assay
99.995% trace metals basis
form
powder
reaction suitability
core: copper
impurities
≤55.0 ppm Trace Metal Analysis
mp
605 °C (lit.)
density
5.62 g/mL at 25 °C (lit.)
Quality Level
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Application
a碘化铜在有机反应中有许多应用,包括活性自由基聚合(原子转移自由基聚合或 ATRP)和交叉偶联反应。CuI 还已经用于制造太阳能电池、光致发光和纳米晶体合成。
wgk
WGK 3
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
target_organs
Thyroid
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
flash_point_f
Not applicable
flash_point_c
Not applicable
Self-assembly of nanometer-scale [Cu24I10L12]14+ cages and ball-shaped Keggin clusters into a (4,12)-connected 3D framework with photoluminescent and electrochemical properties.
Xin-Long Wang et al.
Angewandte Chemie (International ed. in English), 45(44), 7411-7414 (2006-11-07)
Highly Luminescent CuInS2/ZnS Core/Shell Nanocrystals: Cadmium-Free Quantum Dots for In Vivo Imaging
Li, Liang;
Chemistry of Materials, 21(12), 2422-2429 (2009)
Dawei Ma et al.
Accounts of chemical research, 41(11), 1450-1460 (2008-08-14)
Copper-assisted Ullmann-type coupling reactions are valuable transformations for organic synthesis. Researchers have extensively applied these reactions in both academic and industrial settings. However, two important issues, the high reaction temperatures (normally above 150 degrees C) and the stoichiometric amounts of
Fabrication of an Efficient Solid-State Dye-Sensitized Solar Cell
Meng, Q. B.;
Langmuir, 19(9), 3572-3574 (2003)
Virgil Percec et al.
Journal of the American Chemical Society, 128(43), 14156-14165 (2006-10-26)
Conventional metal-catalyzed organic radical reactions and living radical polymerizations (LRP) performed in nonpolar solvents, including atom-transfer radical polymerization (ATRP), proceed by an inner-sphere electron-transfer mechanism. One catalytic system frequently used in these polymerizations is based on Cu(I)X species and N-containing
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