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质量水平
检测方案
97%
形式
liquid
反应适用性
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
折射率
n20/D 1.431 (lit.)
n20/D 1.432
bp
186 °C (lit.)
密度
1.662 g/mL at 25 °C
1.687 g/mL at 25 °C (lit.)
SMILES字符串
Nc1c(F)c(F)c(c(F)c1F)C(F)(F)F
InChI
1S/C7H2F7N/c8-2-1(7(12,13)14)3(9)5(11)6(15)4(2)10/h15H2
InChI key
FJOACTZFMHZHSC-UHFFFAOYSA-N
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其他说明
Used in the Preparation of
- Lactams via palladium-catalyzed olefination of arylamides with benzylacrylate, followed by 1,4-conjugate addition
- N-(fluorinated aryl)benzamides as substrates for regioselective C-H amination reactions with O-benzoylhydroxylamines
- Substituted succinimides via palladium-catalyzed carbonylation of N-aryl amides
- N-aryl cyclopropanecarboxamide substrates and various amino acid ligands for palladium-catalyzed C-H activation of cyclopropanes
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警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
相关内容
The Yu program centers around the discovery of catalytic carbon–carbon and carbon–heteroatom bond forming reactions based on C–H activation. Target transformations are selected to enable 1) the use of simple and abundant starting materials such as aliphatic acids, amines and alcohols, and 2) disconnections that drastically shorten the synthesis of a drug molecule or a major class of biologically active compounds.
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