791601
mIBX
别名:
1,3-Dihydro-1-hydroxy-3-oxo-1,2-benziodoxole-4-carboxylic acid 1-oxide
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关于此项目
经验公式（希尔记法）:
C8H5IO6
分子量:
324.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
InChI key
YGABLFBBILUMGY-UHFFFAOYSA-N
SMILES string
O=C(O1)C2=C(C(O)=O)C=CC=C2I1(O)=O
InChI
1S/C8H5IO6/c10-7(11)4-2-1-3-5-6(4)8(12)15-9(5,13)14/h1-3H,(H,10,11)(H,13,14)
form
powder
reaction suitability
reagent type: oxidant
functional group
carboxylic acid, iodo
storage temp.
−20°C
General description
mIBX (modified 2-iodoxybenzoic acid), a water-soluble hypervalent iodine compound, can be prepared from 3-nitrophthalic acid. mIBX is an environment-friendly oxidizing agent that allows selective oxidation of allylic and benzylic alcohols in water.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Synthesis and oxidation reactions of a user-and eco-friendly hypervalent iodine reagent.
Thottumkara AP and Vinod TK.
Tetrahedron Letters, 43(4), 569- 572 (2002)
Hypervalent iodine reagents for the oxidation of alcohols and their application to complex molecule synthesis.
Tohma H and Kita Y.
Advanced Synthesis & Catalysis, 346(2-3), 111-124 (2004)
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