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主要文件

791571

Sigma-Aldrich

异丙基 p -甲苯磺酸盐

97%

别名:

异丙基甲苯

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About This Item

经验公式(希尔记法):
C10H14O3S
CAS号:
分子量:
214.28
EC 号:
MDL编号:
UNSPSC代码:
12352100
NACRES:
NA.22

质量水平

方案

97%

表单

liquid

折射率

n20/D 1.503

密度

1.142 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

[S](=O)(=O)(Oc1ccc(cc1)C)C(C)C

InChI

1S/C10H14O3S/c1-8(2)14(11,12)13-10-6-4-9(3)5-7-10/h4-8H,1-3H3

InChI key

MUTOLSSCMLECRU-UHFFFAOYSA-N

应用

对甲苯磺酸异丙酯可用作以下反应的反应物:
  • 在三乙胺存在下进行胺的烷基化反应
  • 在四丁基氢氧化铵存在下进行环状硫异羟肟酸(thiohydroxamic acid)的O-烷基化
  • 在2-环己基乙基溴化镁和二氯二茂锆的存在下与苯乙烯反应合成3-甲基-2-苯基-1-丁醇

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Spin trapping of alkoxyl radicals generated from 5-methyl and 5-aryl-3-alkoxy-4-methylthiazole-2 (3H)-thiones in photochemically induced and microwave-initiated reactions
Gross A, et al.
Tetrahedron, 64, 10882-10889 (2008)
J de Armas et al.
Organic letters, 3(13), 2097-2100 (2001-06-22)
[reaction: see structure] The first examples of efficient electrophilic Zr-catalyzed carbomagnesations are disclosed, where in contrast to previous catalytic carbomagnesations the alkyl moiety of the electrophile is transferred (vs that of the Grignard reagent). The identity of the Grignard reagent
B Y P Tay et al.
International journal of cosmetic science, 38(6), 627-633 (2016-05-14)
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Satsuki Chikura et al.
Mutation research, 811, 110-116 (2016-12-10)
As part of a collaborative study in the Mammalian Mutagenicity Study group of the Japanese Environmental Mutagen Society, we evaluated the in vivo mutagenicity of isopropyl p-toluenesulfonate (IPTS) using a peripheral blood Pig-a assay in rats. Pig-a mutant frequency (MF)

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