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Merck
CN

791040

Sigma-Aldrich

Zinc n-propylsulfinate

95% (H-NMR)

别名:

Baran NPS Reagent, Bis[(propylsulfinyl)oxy]zinc

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About This Item

经验公式(希尔记法):
C6H14O4S2Zn
CAS号:
分子量:
279.69
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22

方案

95% (H-NMR)

表单

solid

反应适用性

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

mp

80-105 °C

官能团

sulfinic acid

储存温度

2-8°C

SMILES字符串

CCCS(O[Zn]OS(CCC)=O)=O

InChI

1S/2C3H8O2S.Zn/c2*1-2-3-6(4)5;/h2*2-3H2,1H3,(H,4,5);/q;;+2/p-2

InChI key

AVEWLRYVGNMIHD-UHFFFAOYSA-L

应用

Zinc n-propylsulfinate (NPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified

商品

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

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