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Merck
CN

790796

Sigma-Aldrich

Zinc benzylsulfinate

别名:

Zinc benzylsulfinate, Baran BNS Reagent

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About This Item

经验公式(希尔记法):
C14H14O4S2Zn
CAS号:
分子量:
375.78
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22

表单

solid

反应适用性

reaction type: Alkylations
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

56 °C (Decomposition)

储存温度

2-8°C

SMILES字符串

O=S(O[Zn]OS(CC1=CC=CC=C1)=O)CC2=CC=CC=C2

InChI

1S/2C7H8O2S.Zn/c2*8-10(9)6-7-4-2-1-3-5-7;/h2*1-5H,6H2,(H,8,9);/q;;+2/p-2

InChI key

AHSIXHPQMGLVIG-UHFFFAOYSA-L

应用

Zinc benzylsulfinate (BNS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

其他说明

may contain up to 1 mole eq ZnCl2

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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访问文档库

Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified

商品

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

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