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About This Item
经验公式（希尔记法）:
C17H23NO5
CAS号:
分子量:
321.37
Beilstein:
3624582
MDL编号:
UNSPSC代码:
12352209
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
方案
≥98.0% (HPLC)
表单
powder
反应适用性
reaction type: Boc solid-phase peptide synthesis
应用
peptide synthesis
储存温度
2-8°C
SMILES字符串
CC(C)(C)OC(=O)N[C@@H](Cc1ccc(OCC=C)cc1)C(O)=O
InChI
1S/C17H23NO5/c1-5-10-22-13-8-6-12(7-9-13)11-14(15(19)20)18-16(21)23-17(2,3)4/h5-9,14H,1,10-11H2,2-4H3,(H,18,21)(H,19,20)/t14-/m0/s1
InChI key
YIRRNENSHUFZBH-AWEZNQCLSA-N
应用
Due to gem-dimethyl substituent effect, Boc-Tyr(Allyl)-OH is found to be resistant to Claisen rearrangement in water.
其他说明
烯丙基侧链保护酪氨酸；用于经复分解反应制得非天然氨基酸的结构单元
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
A Loffet et al.
International journal of peptide and protein research, 42(4), 346-351 (1993-10-01)
Allyl and allyloxycarbonyl groups are used for the side-chain protection of amino acids. The protecting groups may be selectively cleaved using the reagent HSnBu3 under palladium catalysis. The preparation of Boc and Fmoc series of protected amino acids is described.
Aromatic Claisen Rearrangements of O?Prenylated Tyrosine and Model Prenyl Aryl Ethers: Computational Study of the Role of Water on Acceleration of Claisen Rearrangements.
Osuna S, et al.
European Journal of Organic Chemistry, 2013(14), 2823-2831 (2013)
Angewandte Chemie (International Edition in English), 114, 2964-2964 (2002)
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