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检测方案
≥95.0% (HPLC)
形式
solution
浓度
~0.5 M in tert-butyl methyl ether
杂质
≤2.0% water
储存温度
−20°C
SMILES字符串
Brc1ccccc1N=[N+]=[N-]
InChI
1S/C6H4BrN3/c7-5-3-1-2-4-6(5)9-10-8/h1-4H
InChI key
QOVQEONXPGQIHT-UHFFFAOYSA-N
一般描述
1-Azido-2-bromobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions. It can also undergo palladium-catalyzed cross-coupling with arylboronic acids to form the corresponding azido-bis-aryl derivatives.
应用
Review
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 1
WGK
WGK 3
闪点(°F)
-27.4 °F
闪点(°C)
-33 °C
法规信息
新产品
First Suzuki?Miyaura type cross-coupling of ortho-azidobromobenzene with arylboronic acids and its application to the synthesis of fused aromatic indole-heterocycles
Pudlo M, et al.
Tetrahedron, 63(41), 10320-10329 (2007)
Stefan Bräse et al.
Angewandte Chemie (International ed. in English), 44(33), 5188-5240 (2005-08-16)
Since the discovery of organic azides by Peter Griess more than 140 years ago, numerous syntheses of these energy-rich molecules have been developed. In more recent times in particular, completely new perspectives have been developed for their use in peptide
Cu-catalyzed azide? alkyne cycloaddition
Meldal M & Torn?e CW
Chemical Reviews, 108(8), 2952-3015 (2008)
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