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Merck
CN

775118

Sigma-Aldrich

硼烷二甲基硫醚络合物 溶液

greener alternative

1.0 M in 2-methyltetrahydrofuran

别名:

BMS, 三氢 [硫代双 [甲烷]] 硼

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About This Item

线性分子式:
(CH3)2S · BH3
CAS号:
分子量:
75.97
Beilstein:
3663489
MDL编号:
UNSPSC代码:
12352112
PubChem化学物质编号:
NACRES:
NA.22

表单

liquid

质量水平

反应适用性

reagent type: reductant

环保替代产品特性

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

浓度

1.0 M in 2-methyltetrahydrofuran

密度

0.844 g/mL at 25 °C

官能团

thioether

环保替代产品分类

储存温度

2-8°C

SMILES字符串

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI key

RMHDLBZYPISZOI-UHFFFAOYSA-N

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一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

应用

用作区域选择性还原剂的反应物

涉及的反应物:
  • 硼氢化/氧化
笼状化合物的合成
Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.
For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane

包装

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律信息

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1

补充剂危害

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

闪点(°F)

9.3 °F

闪点(°C)

-12.6 °C

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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