77429
(R)-(-)-α-水芹烯
≥95.0% (sum of enantiomers, GC)
别名:
(-)-1,5-对孟二烯, (R)-5-异丙基-2-甲基-1,3-环己二烯
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关于此项目
经验公式（希尔记法）:
C10H16
化学文摘社编号:
分子量:
136.23
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-167-6
Beilstein/REAXYS Number:
2497824
MDL number:
Assay:
≥95.0% (sum of enantiomers, GC)
Form:
liquid
InChI key
OGLDWXZKYODSOB-SNVBAGLBSA-N
InChI
1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4-6,8,10H,7H2,1-3H3/t10-/m1/s1
SMILES string
CC(C)[C@H]1CC=C(C)C=C1
assay
≥95.0% (sum of enantiomers, GC)
form
liquid
optical activity
[α]20/D −225±5°, c = 10% in diethyl ether
bp
171-174 °C (lit.)
density
0.844 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Quality Level
General description
(R)-(-)-α-水芹烯是一种单萜衍生物。
Application
(R)-(-)-α-水芹烯可与2-萘基乙炔羧酸进行[4+2]环加成反应形成手性二烯，其可作为铑催化的不对称加成反应的配体。 它可用于合成（1S，5R）-5-（1-甲基乙基）-2-亚甲基-3-环己烯-1-基氢过氧化物，还原形式为 反式-yabunikkeol。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Sens. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Intrazeolite photo-oxygenation of (R)-(-)-a-phellandrene.
Stratakis M and Sofikiti N.
J. Chem. Res. (M), 2002(8), 374-375 (2002)
Chiral diene ligands for asymmetric catalysis.
Hayashi T.
Aldrichimica Acta, 42(2), 31-38 (2009)
Huai-sheng Hu et al.
Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 32(1), 67-70 (2009-05-19)
The chemical constituents and antimicrobial activity of the essential oil from Acanthopanax brachypus were studied. The essential oil was extracted from the stem of A. brachypus by steam distillation, and its antimicrobial activity was tested in vitro. The chemical constituents
M Miyazawa et al.
Journal of agricultural and food chemistry, 48(7), 2893-2895 (2000-07-18)
gamma-Terpinene was mixed in artificial diet at a concentration of 1 mg/g of diet, and the diet was fed to the last instar larvae of common cutworm (Spodoptera litura). Metabolites were recovered from frass and analyzed spectroscopically. gamma-Terpinene was transformed
Gökalp İşcan et al.
Chemistry & biodiversity, 9(8), 1525-1532 (2012-08-18)
Terpene derivatives converted by microbial biotransformation constitute an important resource for natural pharmaceutical, fragrance, and aroma substances. In the present study, the monoterpene α-phellandrene was biotransformed by 16 different strains of microorganisms (bacteria, fungi, and yeasts). The transformation metabolites were
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