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质量水平
方案
90%
表单
solid
mp
>300 °C
SMILES字符串
[K+].F[B-](F)(F)CCC=C
InChI
1S/C4H7BF3.K/c1-2-3-4-5(6,7)8;/h2H,1,3-4H2;/q-1;+1
InChI key
UPXWGXKSNOQOKH-UHFFFAOYSA-N
应用
Organotrifluoroborate involved in:
Organotrifluoroborates as versatile and stable boronic acid surrogates
- Catalytic allylboration
- Stereoselective nucleophilic addition
- Pd-catalyzed heterocyclizations
- Oxidation reactions and Oxidative Mannich reactions
- Cross-coupling reactions
Organotrifluoroborates as versatile and stable boronic acid surrogates
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Catalytic activation of pinacolyl allylboronate with indium(I): development of a general catalytic allylboration of ketones.
Angewandte Chemie (International ed. in English), 46(31), 5909-5912 (2007-06-20)
The development of a Selectfluor-mediated oxidative Mannich reaction
Tetrahedron Letters, 52, 3543-3546 (2011)
Oxidation of alkyl trifluoroborates: an opportunity for tin-free radical chemistry.
Angewandte Chemie (International ed. in English), 49(46), 8721-8723 (2010-10-12)
A new organic transformation by introducing crotyl/allyltrifluoroborates in cross-coupling reaction with aroyl chlorides
Tetrahedron Letters, 52, 5090-5093 (2011)
Stereoselective nucleophilic addition of potassium alkyltrifluoroborates to cyclic N-acyliminium ions: a simple and mild approach to chiral 5-alkylpyrrolidin-2-ones
Australian Journal of Chemistry, 62, 909-916 (2009)
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