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Merck
CN

772410

PTB7

greener alternative

average Mw 80,000-200,000, PDI ≤3.0

别名:

聚({4,8-双 [(2-乙基己基)氧] 苯并 [1,2-b:4,5-b′]二硫苯-2,6-二基 }{3-氟-2-[(2-乙基己基)羰基]噻吩并[3,4-b]噻吩二基})

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经验公式(希尔记法):
(C41H53FO4S4)n
化学文摘社编号:
NACRES:
NA.23
UNSPSC Code:
12352103
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产品名称

PTB7, average Mw 80,000-200,000, PDI ≤3.0

description

Band gap: 1.84 eV

form

solid

mol wt

average Mw 80,000-200,000

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λmax

680 nm (thin film)

orbital energy

HOMO -5.15 eV 
LUMO -3.31 eV 

Mw/Mn

2.4 +/- 0.6

PDI

≤3.0

greener alternative category

Quality Level

Application

它主要用作活化层,通过增加光吸收和提高电子迁移率来提升聚合太阳能电池(PSC)的整体性能。
高效有机太阳能电池 (OPV)
OPV 器械结构:ITO/PEDOT:PSS/PTB7:PC71BM/Ca/Al
  • JSC = 14.9 mA/cm2
  • VOC = 0.75 V
  • FF = 0.69
  • PCE = 7.4%

General description

PTB7是一种可用于有机太阳能电池的半导体聚合物,能效为9.15%。它具有窄光学带隙和优异的π-π共轭体系,可作为电子供体与富勒烯形成纳米复合物。
我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。本品属于绿色替代产品的赋能型产品,符合“节能设计”原则。空穴传输有机材料与吸收层的能级排列完美匹配,因此实现高效的电荷收集,它在环境条件下易于降解。点击此处 了解更多信息。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Highly efficient tandem polymer photovoltaic cells
Sista S, et al.
Advanced Materials, 22(3), 380-383 (2010)
Absolute measurement of domain composition and nanoscale size distribution explains performance in PTB7: PC71BM solar cells
Collins BA, et al.
Advanced Energy Materials, 3(1), 65-74 (2013)
ZnO: CNT assisted charge transport in PTB7: PCBM blend organic solar cell
Oseni SO, et al.
Journal of alloys and compounds, 748(1), 216-222 (2018)
Effect of Active Layer Thickness on the Performance of Polymer Solar Cells Based on a Highly Efficient Donor Material of PTB7-Th
Zang Y, et al.
The Journal of Physical Chemistry C, 122(29), 16532-16539 (2018)
Efficient organic solar cells based on PTB7/PC71BM blend film with embedded different shapes silver nanoparticles into PEDOT: PSS as hole transporting layers
Chen C, et al.
Organic Electronics, 62, 95-101 (2018)

商品

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

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