771406
三氟甲烷亚磺酸锌
别名:
TFMS, 双（（三氟甲基）亚磺酰基）氧）锌, 氟乙酸三氟甲基化试剂
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关于此项目
经验公式（希尔记法）:
C2F6O4S2Zn
化学文摘社编号:
分子量:
331.53
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
InChI
1S/2CHF3O2S.Zn/c2*2-1(3,4)7(5)6;/h2*(H,5,6);/q;;+2/p-2
InChI key
UANOWFITUWBPCF-UHFFFAOYSA-L
SMILES string
FC(F)(F)S(=O)O[Zn]OS(=O)C(F)(F)F
form
solid
reaction suitability
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
mp
151-157 °C
storage temp.
2-8°C
Quality Level
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Application
三氟甲烷亚磺酸锌 (TFMS) 是 Phil Baran 开发的亚磺酸锌工具箱的一部分，用于杂环的简单快速多样化。
杂环化合物的实用固有碳氢功能化
在 Phil S. Baran 教授的 教授和产品门户网站 了解更多信息。
杂环化合物的实用固有碳氢功能化
在 Phil S. Baran 教授的 教授和产品门户网站 了解更多信息。
Other Notes
本产品常见问题 。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified
商品
Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.
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