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Merck
CN

765007

Sigma-Aldrich

2,2′,7,7′-Tetrakis(N,N-diphenylamino)-9,9-spirobifluorene

99% (HPLC)

别名:

N2,N2,N2′,N2′,N7,N7,N7′,N7′-octaphenyl-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine, Spiro-TAD

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About This Item

经验公式(希尔记法):
C73H52N4
分子量:
985.22
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:

检测方案

99% (HPLC)

形式

powder

mp

275-280 °C

λmax

378 μm in THF

SMILES字符串

c1ccc(cc1)N(c2ccccc2)c3ccc4-c5ccc(cc5C6(c4c3)c7cc(ccc7-c8ccc(cc68)N(c9ccccc9)c%10ccccc%10)N(c%11ccccc%11)c%12ccccc%12)N(c%13ccccc%13)c%14ccccc%14

InChI

1S/C73H52N4/c1-9-25-53(26-10-1)74(54-27-11-2-12-28-54)61-41-45-65-66-46-42-62(75(55-29-13-3-14-30-55)56-31-15-4-16-32-56)50-70(66)73(69(65)49-61)71-51-63(76(57-33-17-5-18-34-57)58-35-19-6-20-36-58)43-47-67(71)68-48-44-64(52-72(68)73)77(59-37-21-7-22-38-59)60-39-23-8-24-40-60/h1-52H

InChI key

MQRCTQVBZYBPQE-UHFFFAOYSA-N

应用

Hole transport materials comprised of a spiro center between two charge transport material (CTM) moieties. This molecular conformation improves the thermal stability of the amorphous state, without significantly altering the charge-transport properties.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Michael Grimann et al.
The journal of physical chemistry. B, 124(26), 5507-5516 (2020-06-05)
Understanding phase separation phenomena in blends of organic electron acceptor and donor materials is of special interest in the context of organic optoelectronic applications. In this study, we focus on the phase behavior of a special class of spiro-linked compounds
Advanced Materials, 12, 1060-1063 (2000)

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