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Merck
CN

763888

Sigma-Aldrich

2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene

95% (HPLC)

别名:

2,2′,7,7′-Tetrabromo-9,9′-spirobi[9H-fluorene]

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About This Item

经验公式(希尔记法):
C25H12Br4
分子量:
631.98
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

检测方案

95% (HPLC)

形式

solid

mp

395-400 °C

SMILES字符串

Brc1ccc2-c3ccc(Br)cc3C4(c2c1)c5cc(Br)ccc5-c6ccc(Br)cc46

InChI

1S/C25H12Br4/c26-13-1-5-17-18-6-2-14(27)10-22(18)25(21(17)9-13)23-11-15(28)3-7-19(23)20-8-4-16(29)12-24(20)25/h1-12H

InChI key

MASXXNUEJVMYML-UHFFFAOYSA-N

一般描述

2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene is a spirobifluorene (SBF) derivative and is used as a blue-emitting material in electroluminescent devices. The spirobifluorene linkage in the molecule helps in decreasing the crystallization tendency and also increases the colour stability by preventing the formation of aggregates or excimers. They possess high photoluminescence efficiency and good chemical stability.

应用

Blue light emitting material in Organic Light Emitting Diodes (OLEDs).

特点和优势

High glass-transition temperature, excellent thermal stability, soluble in common organic solvents, multi-layer devices can be fabricated by thermal cross-linking of cast films. Easy colour tunability through the introduction of low band gap co-monomers.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Organic Light Emitting Diode (OLED) materials from spirobifluorene derivatives
R. N. Jana, S. Chakraborty, R. Banerjee
Physics Express, 4(2) (2014)
Amorphous poly-2, 7-fluorene networks
Marsitzky, D., Murray, J., Scott, J. C., & Carter, K. R.
Chemistry of Materials, 13(11), 4285-4289 (2001)
Shugo Sakaguchi et al.
The journal of physical chemistry. B, 122(36), 8614-8623 (2018-08-23)
Nanostructures composed of conjugated polymers or π-conjugated molecules provide sensing platforms with large specific surface areas. One of the feasible approaches to accessing such nanostructured miniaturized sensors with ultrahigh sensitivity is to develop a network of organic nanowires with optical/electronic

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